This monograph was reprinted by the American Crystallographic Association, successor to the American Society for X-Ray and Electron Diffraction, May, 1966.
This Monograph has two aspects. On the one hand, it is presented as a contribution to the study of structure factors — or Fourier transforms — of atomic groupings which occur frequently in a wide variety of crystals, both organic and inorganic. Thus special attention is given to such cases as tetrahedral, octahedral and hexagonal arrays of like atoms. A section on the structure factors of small crystals is also included.
On the other hand, it is presented as a contribution to the x-ray analysis of megamolecular crystals as yet studied by few but destined, it would seem, to play an important role in the crystallography of the future. Megamolecular crystals confront crystallography with a new problem, since the structure of the molecules and indeed, to some extent, even the composition of the molecules is unknown. It is the belief of the Author that a systematic study of what may be called the language of structure factors is a necessary preliminary to the interpretation of the intensity maps of crystals made up of megamolecules of unknown structure. In the sequel the structure factors of distributions of different structural types are recorded. Such mathematical facts provide material for the study of the relationship between distributions and their structure factors — the fundamental theme throughout this Monograph.
The Marine Biological Laboratory
Woods Hole, Mass., August 1, 1945
Appendix. Fourier Series and Fourier's Integral Theorem